Ms. Mills et al., Pesticide degradation in subsurface soils: Risk assessment and regulatory considerations, HUMAN AND ENVIRONMENTAL EXPOSURE TO XENOBIOTICS, 1999, pp. 737-745
The Acetochlor Registration Partnership (ARP) has undertaken an extensive p
rogramme to determine subsoil degradation rates under undisturbed field con
ditions and traditional laboratory incubation conditions, using acetochlor
as a test compound. The results show rapid and comparable rates of degradat
ion of acetochlor in field- and laboratory-incubated subsoils, that often e
xceed surface degradation rates. The leaching models used to perform ground
water risk assessments (e.g. PELMO, PESTLA, MACRO-DB, PRZM and the FOCUS EU
leaching scenarios), have provision for inclusion of subsoil degradation r
ates. However, conservative or zero default subsoil degradation values are
typically used as no other alternative is available. Results presented in t
his paper show that these default values may significantly underestimate th
e true subsoil degradation contribution and therefore not accurately predic
t pesticide concentrations in groundwater. This paper reviews the latest fi
ndings in subsoil degradation research, summarises the subsoil degradation
data generated under the ARP programme and demonstrates the importance of t
he inclusion of subsoil degradation data in mathematical models and thereby
in the registration of pesticides in Europe.