C-S bond cleavage in CpRu(PPh3)(2)SCH2CH=CH2 to give the trimer (CpRu)3(mu(3)-S)(2)(mu-SCH2CH=CH2)

Citation
A. Shaver et al., C-S bond cleavage in CpRu(PPh3)(2)SCH2CH=CH2 to give the trimer (CpRu)3(mu(3)-S)(2)(mu-SCH2CH=CH2), INORG CHEM, 38(25), 1999, pp. 5913
Citations number
31
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
25
Year of publication
1999
Database
ISI
SICI code
0020-1669(199912)38:25<5913:CBCICT>2.0.ZU;2-D
Abstract
C-S Bond Cleavage in CpRu(PPh3)(2)SCH2CH=CH2 To Give the Trimer (CPRu)(3)(m u(3)-S)(2)(mu-SCH2CH=CH2) CpRu(PPh3)(2)SCH2CH=CH2 (1) loses two PPh3 ligand s in refluxing toluene and undergoes C-S bond cleavage to give the sulfide- bridged trimer (CpRu)(3)(mu(3)-S)(2)(mu SCH2CH=CH2) (6).