Partial degradation of the new exo-heterodisubstituted carborane derivatives with d(10) transition metal ions (Cu, Au)

Authors
Teixidor, F Benakki, R Vinas, C Kivekas, R Sillanpaa, R
Citation
F. Teixidor et al., Partial degradation of the new exo-heterodisubstituted carborane derivatives with d(10) transition metal ions (Cu, Au), INORG CHEM, 38(25), 1999, pp. 5916
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
25
Year of publication
1999
Database
ISI
SICI code
0020-1669(199912)38:25<5916:PDOTNE>2.0.ZU;2-H
Abstract
Partial Degradation of the New exo-Heterodisubstituted Carborane Derivative s with d(10) Transition Metal Ions (Cu, Au) Reaction of the closo heterodis ubstituted [1-PPh2-2-SR-1,2-C2B10H10] compounds with d(10) transition metal complexes, [MCl(PPh3)(n)] (M = Cu, n = 2; M = Au, n = 1), in ethanol affor ds the complexes [M(7-PPh2-8-SR-7,8-C2B9H10)(PPh3)(n)] (M = Cu, Au). The cr ystal structure of [Au(7-PPH2-8-SBz-7,8-C2B9H10)(PPh3)] displays a linear g eometry where the carborane ligand coordinates the Au(1) just through the p hosphino group.