Polybis(1-methyl-2-thioimidazolate)iron(II): Crystal structure and magnetic properties of a one-dimensional material exhibiting ferromagnetic ordering below 8 K

Authors
Rettig, SJ Sanchez, V Storr, A Thompson, RC Trotter, J
Citation
Sj. Rettig et al., Polybis(1-methyl-2-thioimidazolate)iron(II): Crystal structure and magnetic properties of a one-dimensional material exhibiting ferromagnetic ordering below 8 K, INORG CHEM, 38(25), 1999, pp. 5920
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
25
Year of publication
1999
Database
ISI
SICI code
0020-1669(199912)38:25<5920:PCSAM>2.0.ZU;2-3
Abstract
Polybis(1-methyl-2-thioimidazolate)iron(II): Crystal Structure and Magnetic Properties of a One-Dimensional Material Exhibiting Ferromagnetic Ordering below 8 K. The title compound has a rodlike 1-D structure in which iron io ns are double bridged by 1-methyl-2-thioimidazolate ligands and the metal c hromophores alternate along the chain between FeS4 and FeN4. Antiferromagne tic intrachain coupling with spin canting generates residual spin on the ch ains that undergo long-range ferromagnetic order below 8 K.