POLY(ALKYL THIOPHENE-3-CARBOXYLATES) - SYNTHESIS, PROPERTIES AND ELECTROLUMINESCENCE STUDIES OF A POLYTHIOPHENE WITH A CARBONYL GROUP ATTACHED TO THE RING
M. Pomerantz et al., POLY(ALKYL THIOPHENE-3-CARBOXYLATES) - SYNTHESIS, PROPERTIES AND ELECTROLUMINESCENCE STUDIES OF A POLYTHIOPHENE WITH A CARBONYL GROUP ATTACHED TO THE RING, Synthetic metals, 85(1-3), 1997, pp. 1235-1236
Improved synthetic methodology for poly(hexyl and octyl thiophene-3-ca
rboxylates) (1a and 1b) is reported. (M) over bar(n)=6700 and 9400 ((M
) over bar(W)/(M) over bar(n)=2.5 and 3.2), lambda(max) for fluorescen
ce emission = 600 and 610 nm and for electroluminescence = 600 and 615
nm, for la and Ib respectively. The H-1 NMR spectra showed more aroma
tic peaks than can be explained using triads, and it is suggested that
pentads, involving longer range influences, must be considered to exp
lain the spectra. Electroluminescence efficiencies of ca. 0.02% were o
bserved for devices made from la and b. A bilayer device of ITO/poly(3
-octylthiophene)/1b/Al emitted at 646 nm, where poly(3-octylthiophene)
emits. The efficiency was low but was an order of magnitude greater t
han for poly(3-octylthiophene) itself.