We present results of the generation and detection of electroluminesce
nce in thin ParaHexaPhenyl(PHP)-layers. For the characterization we us
e a Scanning-Tunneling-Microscope (STM). PHP can be used as a very sta
ble emitting layer in blue Light-Emitting-Devices (LED's). The mechani
sms of electroluminescence in PHP, which is an organic semiconductor,
differ from those in conventional inorganic devices, therefore it is o
f high interest to investigate the physics of the processes. With an S
TM it is possible to investigate both the topography and optical prope
rties of semiconducting surfaces in sub-micron dimensions. Hence relat
ions between the generation of electroluminescence and structural prop
erties of the semiconducting layers (highly oriented or disordered) ca
n be found. Electrons were injected by the scanning tip, the holes by
the conducting substrate (Indium-Tin-Oxide ITO on glass). The luminesc
ence emission is limited to very small areas (a few nm(2)), making the
results interesting for applications such as nano-lightsources.