Comparison of capillary electrophoresis and liquid chromatography for determination of sulfonylurea herbicides in soil

Two analytical methods developed for degradation studies in soil were compa red for the simultaneous determination of sulfonylurea herbicides. The comp ounds were extracted with phosphate buffer from soil samples after purifica tion and enrichment steps by solid-phase extraction. Samples were analyzed by liquid chromatography (LC) or capillary electrophoresis (CE) with UV det ection. Amidosulfuron, bensulfuron-methyl, chlorimuron-ethyl, chlorsulfuron , ethametsulfuron-methyl, metsulfuron-methyl, nicosulfuron, primisulfuron-m ethyl, sulfometuron-methyl, thifensulfuron-methyl, triasulfuron, and triben uron-methyl were separated within 90 and 35 min by LC and CE, respectively. Average recoveries, determined with LC for 5 sulfonylureas in 1-100 mu g/k g soil ranged from 74 to 103%, and those determined with CE for 10 sulfonyl ureas in 2-20 mu g/kg soil ranged from 87 to 105%. Bensulfuron-methyl was r ecovered at lower levels of 52%. The limits of quantitation were 1.0 and 2. 0 mu g/kg soil for LC and CE, respectively, Coefficients of variation were higher for CE than for LC. Although both methods are suitable, the LC metho d, which is more sensitive and accurate than the CE method, is preferred fo r field studies. However, CE, which was shown to be faster with lower opera ting costs and unlimited repeatability of the analysis due to little inject ion volumes, is preferred for laboratory studies.