X-ray scattering by crystals with local lattice rotation fields

Citation
Ri. Barabash et P. Klimanek, X-ray scattering by crystals with local lattice rotation fields, J APPL CRYS, 32, 1999, pp. 1050-1059
Citations number
28
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF APPLIED CRYSTALLOGRAPHY
ISSN journal
00218898 → ACNP
Volume
32
Year of publication
1999
Part
6
Pages
1050 - 1059
Database
ISI
SICI code
0021-8898(199912)32:<1050:XSBCWL>2.0.ZU;2-2
Abstract
X-ray (or neutron) scattering by crystals with local rotation fields arisin g from dislocations is treated on the basis of the formalism of the kinemat ical diffraction theory. Such fields mostly change the intensity distributi on of reflections in the azimuthal plane. Scattering intensity in the azimu thal plane for crystals with one or two sets of different-type dislocation walls, causing local rotations in the lattice, is analysed. In this case th e intensity distribution is close to Lorentzian in the radial direction and to Gaussian in the azimuthal direction. The expressions for the scattering intensity are valid when averaging over a large statistical ensemble of de fects. If this condition is ndt fulfilled, the intensity distribution in th e azimuthal plane will split into several spikes. The mean distance between these spikes in the reciprocal-lattice space is connected with the disorie ntation between the walls. The conditions necessary far such splitting of t he reflection into spikes are considered. The values of the limiting disori entation angle for some common scattering volumes and distances between dis location walls are evaluated.