A model-independent maximum-entropy method for the inversion of small-angle X-ray diffraction patterns

Citation
Ja. Elliott et S. Hanna, A model-independent maximum-entropy method for the inversion of small-angle X-ray diffraction patterns, J APPL CRYS, 32, 1999, pp. 1069-1083
Citations number
32
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF APPLIED CRYSTALLOGRAPHY
ISSN journal
00218898 → ACNP
Volume
32
Year of publication
1999
Part
6
Pages
1069 - 1083
Database
ISI
SICI code
0021-8898(199912)32:<1069:AMMMFT>2.0.ZU;2-K
Abstract
A model-independent maximum-entropy method is presented which will produce a structural model from small-angle X-ray diffraction data of disordered sy stems using no other prior information. In this respect, it differs from co nventional maximum-entropy methods which assume the form of scattering enti ties a priori. The method is demonstrated using a number of different simul ated diffraction patterns, and applied to real data obtained from perfluori nated ionomer membranes, in particular Nafion(TM), and a liquid crystalline copolymer of 1,4-oxybenzoate and 2,6-oxynaphthoate (B-N).