M. Rikukawa et al., ELECTROCHEMICAL AND SENSING PROPERTIES OF ENZYME-POLYPYRROLE MULTICOMPONENT ELECTRODES, Synthetic metals, 85(1-3), 1997, pp. 1377-1378
A structurally well-defined multilayer enzyme electrode comprised of a
lipid-modified glucose oxidase and an electrically conductive poly(py
rrole) LB film for detecting glucose was fabricated by using the Langm
uir-Blodgett technique. The voltammetric measurements of these electro
des revealed that the electrically conductive poly(pyrrole) layers cou
ld quantitatively detect the hydrogen peroxide produced by the modifie
d enzyme layers. The amperometric anodic current (at 0.6 V vs. Ag/AgCl
) of the electrode increased with increasing the glucose concentration
. A linear response to glucose concentration was observed in the range
of 15 - 100 mM with a detection limit of 5 mM.