Intracluster hydrogen transfer followed by dissociation in the phenol-(NH3)(3) excited state: PhOH(S-1)-(NH3)(3)-> PhO center dot+(NH4)(NH3)(2)

Authors
Pino, GA Dedonder-Lardeux, C Gregoire, G Jouvet, C Martrenchard, S Solgadi, D
Citation
Ga. Pino et al., Intracluster hydrogen transfer followed by dissociation in the phenol-(NH3)(3) excited state: PhOH(S-1)-(NH3)(3)-> PhO center dot+(NH4)(NH3)(2), J CHEM PHYS, 111(24), 1999, pp. 10747-10749
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
111
Issue
24
Year of publication
1999
Pages
10747 - 10749
Database
ISI
SICI code
0021-9606(199912)111:24<10747:IHTFBD>2.0.ZU;2-7
Abstract
The study of the phenol-(NH3)(3) cluster with two-color two-photon ionizati on shows that the main ion observed with delays between the lasers up to a few hundred nanoseconds is the (NH4)(+)(NH3)(2) fragment, resulting from di rect ionization of the (NH4)(NH3)(2) product coming from the reaction: PhOH (S-1)-(NH3)(3)--> PhO.+(NH4)(NH3)(2). (C) 1999 American Institute of Physic s. [S0021-9606(99)01448-8].