POLYMORPHISM IN KAPPA-(BEDT-TTF)(2)M(CF3)(4)(SOLVENT) SUPERCONDUCTORS

Citation
U. Geiser et al., POLYMORPHISM IN KAPPA-(BEDT-TTF)(2)M(CF3)(4)(SOLVENT) SUPERCONDUCTORS, Synthetic metals, 85(1-3), 1997, pp. 1465-1466
Citations number
6
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
ISSN journal
03796779
Volume
85
Issue
1-3
Year of publication
1997
Pages
1465 - 1466
Database
ISI
SICI code
0379-6779(1997)85:1-3<1465:PIKS>2.0.ZU;2-9
Abstract
A new crystallographic modification (kappa(L)') was found in the BEDT- TTF:M(CF3)(4)(-):solvent (M = Cu, Ag, Au) system. The structure of mon oclinic (BEDT-TTF)(2)Cu(CF3)(4)(1,2-dibromo-1-chloroethane = DBCE) is reported. It differs from the orthorhombic kappa(L)-phase by having al l BEDT-TTF molecules tilted in the same direction with respect to the conducting plane normal, whereas in kappa(L) the tilt direction altern ates between layers.