HYBRID MOLECULAR MATERIALS HAVING CONDUCTING AND MAGNETIC NETWORKS - CHARGE-TRANSFER SALTS BASED ON ORGANIC PI-DONOR MOLECULES AND INORGANIC MAGNETIC CLUSTERS
E. Coronado et al., HYBRID MOLECULAR MATERIALS HAVING CONDUCTING AND MAGNETIC NETWORKS - CHARGE-TRANSFER SALTS BASED ON ORGANIC PI-DONOR MOLECULES AND INORGANIC MAGNETIC CLUSTERS, Synthetic metals, 85(1-3), 1997, pp. 1647-1650
The synthesis and physical characterization of new organic-inorganic h
ybrids formed by conducting and magnetic networks are reported. The cr
ystalline radical salts are formed by BEDT-TTF type donors as conducti
ng component, and by large metaloxide clusters of variable sizes and s
hapes (polyoxometalates) as magnetic component. We also show how these
magnetic clusters can be incorporated in conducting organic polymers
to give hybrid organic/inorganic films.