We present syntheses and properties of several kinds of polyaniline an
d polyaminopyridine derivatives. Polyaniline derivative with a stable
radical group (PDDBO) and iodine-doped (doped-PmAPY) or oxidized polya
minopyridine (PmAPYO) showed one or two ''half-field'' ESR signals due
to Delta m(s) = +/-2, in addition to a signal at central resonance fi
eld. For these polymers was strongly suggested a possibility of spin m
ultiplet state including triplet one.