THE INFLUENCE OF DISORDER ON THE MAGNETIC PHENOMENA IN METALLOPORPHYRIN-BASED MAGNETS

Citation
Ma. Girtu et al., THE INFLUENCE OF DISORDER ON THE MAGNETIC PHENOMENA IN METALLOPORPHYRIN-BASED MAGNETS, Synthetic metals, 85(1-3), 1997, pp. 1703-1704
Citations number
7
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
ISSN journal
03796779
Volume
85
Issue
1-3
Year of publication
1997
Pages
1703 - 1704
Database
ISI
SICI code
0379-6779(1997)85:1-3<1703:TIODOT>2.0.ZU;2-Q
Abstract
We investigate the effects of disorder in the quasi-one-dimensional me talloporphyrin family of molecule-based magnets. These materials are e lectron transfer salts consisting of linear chains of alternating S=2 Mn-III-porphyrin donors and S=1/2 bridging accepters. Studies of the i rreversibilities, and frequency dependence of the ac magnetic suscepti bility suggest a cluster glass-like behavior in certain compounds at l ow temperatures. The role of the intercalated solvent and its relation to any disorder present in the compounds are discussed.