This communication reports the novel idea of using a magnetic field gradien
t to hold magnetic nanoparticles at desired densities in a fixed location (
e.g., on an electrode surface), while metal atoms are deposited electrochem
ically in the interstices between them. Using it, nanocomposites consisting
of gamma-Fe2O3 nanoparticles (with a mean size of about 40 nm) in a copper
metal matrix were reproducibly fabricated, with particle volume fractions
ranging from 0.2% to 50%. These nanocomposites, ceramic magnetic particles
in a conductive metal matrix, are expected to have unusual or enhanced mech
anical, electrical, and magnetic properties.