Infrared and Raman spectra of new molybdenum and tungsten oxyfluoride glasses

Authors
Hager, IZ El-Mallawany, R Poulain, M
Citation
Iz. Hager et al., Infrared and Raman spectra of new molybdenum and tungsten oxyfluoride glasses, J MATER SCI, 34(21), 1999, pp. 5163-5168
Citations number
12
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
JOURNAL OF MATERIALS SCIENCE
ISSN journal
00222461 → ACNP
Volume
34
Issue
21
Year of publication
1999
Pages
5163 - 5168
Database
ISI
SICI code
0022-2461(199911)34:21<5163:IARSON>2.0.ZU;2-L
Abstract
The infrared (400-1200 cm(-1)) and Raman (200-1150 cm( 1)) spectra are repo rted for the new AO(3)-BaF2-RF glasses where A is molybdenum or tungsten an d RF is the alkali fluoride LiF, NaF and mixed LiF-NaF respectively. The ob served absorption bands of each glass series were assigned to their vibrati onal modes. This study has shown that structural units formed in these glas ses include [MoO4] and [WO4] tetrahedra, [MoO6], [WO6], [MoF6] and [WF6] oc tahedra groups. (C) 1999 Kluwer Academic Publishers.