Synergic effect of polymer-supported bimetallic catalysts in the hydrogenation and isomerization of 1-octene

Authors
Liu, CQ Xu, Y Liao, SJ Yu, DR
Citation
Cq. Liu et al., Synergic effect of polymer-supported bimetallic catalysts in the hydrogenation and isomerization of 1-octene, J MOL CAT A, 149(1-2), 1999, pp. 119-123
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN journal
13811169 → ACNP
Volume
149
Issue
1-2
Year of publication
1999
Pages
119 - 123
Database
ISI
SICI code
1381-1169(199912)149:1-2<119:SEOPBC>2.0.ZU;2-S
Abstract
The catalytic properties of the bimetallic catalysts for the hydrogenation and isomerization of 1-octene were investigated. The PVP-PdCl2-1/2Co(OAc)(2 ) bimetallic catalyst reduced by NaBH4 exhibited a remarkable bimetallic sy nergic effect under mild conditions of 40 degrees C and 0.1 MPa. The maximu m turnover frequency (TOFmax, mol H-2/mol Pd min) can be nearly doubled com pared with that of the reaction catalyzed by the monometallic catalyst, and simultaneously the isomerization:of 1-octene to 2-octene and 3-octene was inhibited significantly. (C) 1999 Elsevier Science B.V. All rights reserved .