CRYSTAL AND MOLECULAR-STRUCTURE OF (N-]B) PHENYL [N-METHYLIMINODIACETATE-O,O',N] BORANE

Authors
MANCILLA T HOPFL H BRAVO G CARRILLO L
Citation
T. Mancilla et al., CRYSTAL AND MOLECULAR-STRUCTURE OF (N-]B) PHENYL [N-METHYLIMINODIACETATE-O,O',N] BORANE, Silicon, germanium, tin and lead compounds, 20(1), 1997, pp. 31-36
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Silicon, germanium, tin and lead compounds → ACNP
ISSN journal
07921241
Volume
20
Issue
1
Year of publication
1997
Pages
31 - 36
Database
ISI
SICI code
0792-1241(1997)20:1<31:CAMO
Abstract
The title compound, C11H12BNO4, crystallizes in a trigonal crystal sys tem, space group <R(3)over bar>, With two independent molecules A and B in the asymmetric unit. These molecules show a bicyclooctane structu re with different torsion angles of the junction, -22.3 degrees (C-12- B-1-N-6-C-7) for A and 16.6 degrees (C-62-B-51-N-56-G(57)) for a and N --> B coordination bond distances of 1.662 (3) and 1.673 (3) A,respec tively. They are linked to one another by intermolecular interactions C=O ..... H-CH.