Electrophilic substitution of 1,1,2,2,9,9,10,10-octafluoro[2.2]paracyclophane

Authors
Roche, AJ Dolbier, WR
Citation
Aj. Roche et Wr. Dolbier, Electrophilic substitution of 1,1,2,2,9,9,10,10-octafluoro[2.2]paracyclophane, J ORG CHEM, 64(25), 1999, pp. 9137-9143
Citations number
36
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
00223263 → ACNP
Volume
64
Issue
25
Year of publication
1999
Pages
9137 - 9143
Database
ISI
SICI code
0022-3263(199912)64:25<9137:ESO1>2.0.ZU;2-3
Abstract
Nitration of octafluoro[2.2]paracyclophane (OFP) provides an entry into the synthesis of a series of II monosubstituted OFPs, including the nitro, ami no, chloro, bromo, iodo, hydroxy, and trifluoromethyl compounds. The NMR, m ass spectrometric, and UV spectral properties of all of these derivatives a re presented and discussed, and they are compared with those of its hydroca rbon analogue, [2.2]paracyclophane.