Oscillator strengths of electric dipole transitions in S3+

Authors
Citation
Ss. Tayal, Oscillator strengths of electric dipole transitions in S3+, J PHYS B, 32(22), 1999, pp. 5311-5324
Citations number
22
Categorie Soggetti
Physics
Journal title
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS
ISSN journal
09534075 → ACNP
Volume
32
Issue
22
Year of publication
1999
Pages
5311 - 5324
Database
ISI
SICI code
0953-4075(19991128)32:22<5311:OSOEDT>2.0.ZU;2-J
Abstract
Oscillator strengths and transition probabilities of electric dipole transi tions among the fine-structure levels of the 3s(2)3p, 3s3p(2), 3s(2)3d, 3s( 2)4s, 3p(3), 3s3p3d, 3s(2)4p, 3s(2)4d, 3s(2)4f and 3s3p4s configurations an d of spin-forbidden electric dipole transitions among the levels of the 3s( 2)3p, 3s3p(2) and 3s(2)3d configurations of S3+ are calculated using fairly extensive configuration-interaction wavefunctions. The relativistic correc tions are included through the Breit-Pauli Hamiltonian. The calculated exci ted energies are in close agreement with measurement. Small adjustments to the diagonal elements of the Hamiltonian matrices are made to further bring calculated energy separations between levels as close as possible to the m easured values. The present results are compared with other available calcu lations and experiments and significant discrepancies are noted for some tr ansitions.