As. Alexandrov et Am. Bratkovsky, The essential interactions in oxides and spectral weight transfer in dopedmanganites, J PHYS-COND, 11(48), 1999, pp. L531-L539
We calculate the value of the Frohlich electron-phonon interaction in manga
nites, cuprates, and some other charge-transfer insulators and show that th
is interaction is much stronger than any relevant magnetic interaction. A p
olaron shift due to the Frohlich interaction, which is about 1 eV, suggests
that carriers in those systems are small (bi)polarons at all temperatures
and doping levels, in agreement with the oxygen-isotope effect and other da
ta. An opposite conclusion, recently suggested in the literature, is shown
to be incorrect. The frequency and temperature dependence of the optical co
nductivity of ferromagnetic manganites is explained within the framework of
the bipolaron theory.