A study is presented of the local structure of intense visible light emitti
ng porous SiGe with an initial Ge fraction of 30 at% grown on boron doped-S
i substrates by Solid State Molecular Beam Epitaxy (SS-MBE). Analysis of th
e Extended X-ray Absorption Fine Structure (EXAFS) of the SS-MBE grown SiGe
and their anodized porous counterparts processed under various conditions
is used to obtain a better understanding of the visible light-emitting mech
anism of porous SiGe. In addition, the photoluminescence decay dynamics of
porous SiGe are examined and are found to differ in terms of speed and beha
viour from porous Si. We interpret the origin of visible PL of the porous M
BE SiGe films by considering the quantum confinement effect, as in the inte
rpretation of PL from porous Si, and the evolution of the SiGe Si like-band
structure.