Design of ordered nanostructured solids by template approach is reviewed. A
variety of lattices of semiconductor nanoparticles was formed in the synth
etic opal. The impact of an ensemble periodicity upon the electron and phot
on transport in opal-based lattices has been demonstrated. The conductivity
of such lattices is the product of individual transmission characteristics
of nanostructures, whereas specific collective properties can be seen as t
he small additives. In contrast, the photon transport shows strong collecti
ve behaviour and the photonic energy band structure is formed in addition t
o the electronic band structure. If the optical range photonic bandgap is t
uned in the resonance with the fundamental electronic gap of a composite, t
heir interference leads to the conjugated equilibrium state of the system.