First results of an Electron Energy Loss Spectroscopy in the Near Field (NF
EELS) mode of n(+) porous silicon are described here. Sequences of EELS spe
ctra in the low loss energy range (0-30 eV) were recorded, using a scanning
transmission electron microscope, as the e-beam was scanned across a nano-
hole surrounded by Si platelets. This technique is shown to be very sensiti
ve to spectral and spatial changes in the electromagnetic field distributio
n outside the surface of nanoparticles, governed by their local nature and
shape.