Electrical and optical properties of diode structures based on porous silic
on (PS) and thin films of phenylene vinylene oligomer (PVO) have been studi
ed. Steady-state photoluminescence spectroscopy show that the structure of
the luminescence band depends on the PS morphology. We assign the observed
effect to the morphology-dependent penetration of PVO material into the por
es. Current-voltage characteristics of the PVO/PS diodes are studied and in
terpreted assuming Schottky emission and hopping transport of carriers as p
ossible mechanisms of d.c. electrical conduction.