Diazadithiafulvalenes as electron donor reagents

Citation
T. Koizumi et al., Diazadithiafulvalenes as electron donor reagents, J CHEM S P1, (24), 1999, pp. 3637-3643
Citations number
16
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
0300922X → ACNP
Issue
24
Year of publication
1999
Pages
3637 - 3643
Database
ISI
SICI code
0300-922X(1999):24<3637:DAEDR>2.0.ZU;2-Q
Abstract
Diazadithiafulvalenes act as excellent electron donors to arenediazonium sa lts. The diazadithiafulvalenium radical cations trap primary carbon radical s successfully. However, the diazadithiafulvalenium salts which form, under go rapid ring fragmentation in contrast to their tetrathia counterparts.