Mr. Naimi-jamal et al., Aminosilylation of aldehydes mediated by lithium perchlorate: novel methodfor synthesis of alpha-silylamines, J CHEM S P1, (24), 1999, pp. 3709-3711
alpha-Silylated N,N-dialkylamines 7a-k were easily synthesized in good to e
xcellent yields from aldehydes 1, (trimethylsilyl)dialkylamines 2, and phen
yldimethylsilyllithium 4, diphenylmethylsilyllithium 5, or triphenylsilylli
thium 6, in concentrated ethereal lithium perchlorate solution.