Aminosilylation of aldehydes mediated by lithium perchlorate: novel methodfor synthesis of alpha-silylamines

Citation
Mr. Naimi-jamal et al., Aminosilylation of aldehydes mediated by lithium perchlorate: novel methodfor synthesis of alpha-silylamines, J CHEM S P1, (24), 1999, pp. 3709-3711
Citations number
23
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
0300922X → ACNP
Issue
24
Year of publication
1999
Pages
3709 - 3711
Database
ISI
SICI code
0300-922X(1999):24<3709:AOAMBL>2.0.ZU;2-L
Abstract
alpha-Silylated N,N-dialkylamines 7a-k were easily synthesized in good to e xcellent yields from aldehydes 1, (trimethylsilyl)dialkylamines 2, and phen yldimethylsilyllithium 4, diphenylmethylsilyllithium 5, or triphenylsilylli thium 6, in concentrated ethereal lithium perchlorate solution.