A Moessbauer study of pentavalent iron in a vanadium(V) oxide matrix

Authors
Dedushenko, SK Perfiliev, YD Tcheboukov, DE Pankratov, DA Kiselev, YM
Citation
Sk. Dedushenko et al., A Moessbauer study of pentavalent iron in a vanadium(V) oxide matrix, MENDELEEV C, (5), 1999, pp. 211-212
Citations number
22
Categorie Soggetti
Chemistry
Journal title
MENDELEEV COMMUNICATIONS
ISSN journal
09599436 → ACNP
Issue
5
Year of publication
1999
Pages
211 - 212
Database
ISI
SICI code
0959-9436(199909):5<211:AMSOPI>2.0.ZU;2-A
Abstract
The formation of iron in the 5+ oxidation state was observed in iron-doped vanadium(V) oxide; this state is characterised by a singlet with the isomer shift delta = -0.56 +/- 0.01 mm s(-1) relative to alpha-iron in the Mossba uer spectrum at room temperature.