The detection of X-ray photons scattered through a sample by the Rayleigh a
nd Compton processes is used to perform tomographic images. In the present
paper, we describe a new experimental arrangement and the corresponding rec
onstruction method. The scanning method is similar to the one used for firs
t generation tomographs. A standard reconstruction algorithm gives two inte
rmediate images, corresponding to the Compton and Rayleigh contributions. Q
uantitative comparisons are made with the aim to explain the difference of
sensitivity between each scattering process. On both images artifacts are p
resent, due to photon attenuation. Computing the ratio between those two im
ages produces a map, free from artifacts, which represents the atomic numbe
r Z. Differentiation between polyethylene and an aqueous solution containin
g a low concentration of iodine (0.5 g l(-1)) is easily performed. The expe
riments were carried out at the European Synchrotron Radiation Facility (ES
RF), in Grenoble (France), on line ID15 B. As a result of the very high pho
ton flux, short measurement times (about five seconds per point) are allowe
d, as well as a good spatial resolution. The voxel size is 1 x 1 mm(2) in t
he plane of the slice and 0.3 mm in the third direction. (C) 1999 Elsevier
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