This work is based on a numerical classification method (Forgy's method or
c-means clustering) to investigate flee structure, taking into account a ph
ysically well-founded model. Two different kinds of morphologies, voluminou
s, irregularly shaped, fluffy flocs and dense, regularly shaped, compact, p
ellet-like aggregates, are analyzed. These structures are embedded in glyco
l methacrylate and cut into thin sections by means of a motorized microtome
. Scanning electron microscopic observations show that no serious damage to
the aggregate structure due to the preparation technique is apparent. A se
quence of image analysis steps reduces the total image information of the s
ections, taken by a light microscope, to a few pertinent measurements, appl
icable to cluster analysis. Thus a cluster-cluster aggregation mechanism is
confirmed experimentally. The flee structure is separated into two cluster
s. Cluster 1 consists of six microflocs and cluster 2 is made up of two sub
-units, which are again subdivided into six and three microflocs. The pelle
t-like aggregate is assembled from ten particles. Further interpretation of
aggregate growth history remains unconsidered owing to the expected errors
. In a second paper more aspects concerning cluster analysis of flocs will
be published.