Quenching of the exciton luminescence of GaN epitaxial films and GaN/AlGaN
quantum wells in an electric field is observed and attributed to impact ion
ization of excitonic states by hot electrons. It is found that impurity sca
ttering rules the momentum relaxation of electrons rather than the acoustic
phonon scattering. The effective mean free path of hot electrons l(eff) is
estimated. The value of l(eff) for quantum wells appears to be one order o
f magnitude larger than that for epitaxial films.