Room-temperature photoreflectance spectroscopy is performed on a series of
GaN-AlGaN quantum wells grown by molecular beam epitaxy. We show that the p
otentialities of this powerful investigation method previously demonstrated
on many low-dimensional systems can be extended to nitride-based quantum w
ells for accurate large-scale characterisation. In particular, this techniq
ue allows us to get rid of optical interferences that usually prevent the o
bservation of free-exciton transitions below the band-gap of GaN. Such tran
sitions occur in wide quantum wells, due to large built-in electric fields
which also quench the oscillator strength of the transitions. Also, this te
chnique allows us to magnify the features of confined excited states, which
are difficult to observe by standard reflectance.