Chemistry of bicymantrenyl 7. Mercuration of bicymantrenyl and reactions with aprotic acids

Authors
Ginzburg, AG Suprunovich, SV Sokolov, VI
Citation
Ag. Ginzburg et al., Chemistry of bicymantrenyl 7. Mercuration of bicymantrenyl and reactions with aprotic acids, RUSS CHEM B, 48(9), 1999, pp. 1733-1737
Citations number
15
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
9
Year of publication
1999
Pages
1733 - 1737
Database
ISI
SICI code
1066-5285(199909)48:9<1733:COB7MO>2.0.ZU;2-S
Abstract
Bicymantrenyl, (CO)(3)MnC5H4C5H4Mn(CO)(3), can be mercurated under the acti on of 8 moles of mercury trifluoroacetate in CH2Cl2 to give an octamercuric derivative. Mono- and diphosphine derivatives of bicymantrenyl react with mercury trifluoroacetate and with tin tetrachloride to give adducts at one or two manganese atoms.