Synthesis of rhodacarborane halide complexes [(eta-9-Me2S-7,8-C2B9H10)RhX2](2) (X = Cl, Br, or I)

Authors
Kudinov, AR Meshcheryakov, VI Petrovskii, PV Rybinskaya, MI
Citation
Ar. Kudinov et al., Synthesis of rhodacarborane halide complexes [(eta-9-Me2S-7,8-C2B9H10)RhX2](2) (X = Cl, Br, or I), RUSS CHEM B, 48(9), 1999, pp. 1794-1795
Citations number
12
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
9
Year of publication
1999
Pages
1794 - 1795
Database
ISI
SICI code
1066-5285(199909)48:9<1794:SORHC[>2.0.ZU;2-T
Abstract
The reactions of the complex (eta-9-Me2S-7,8-C2B9H10)Rh(eta-cod) (cod is 1, 5-cyclo-octadiene) with HX acids (X = Cl, Pr, or I) in acetone afforded rho dacarborane halide complexes [(eta-9-Me2S-7,8-C2B9H10)RhX2](2) Which are ca rborane analogs of cyclopentadienyl halide rhodium complexes [(eta-C5R5)RhX 2](2).