Cis 2,6-Diphenyltetrahydrothiapyranone (1) was subjected to Wittig reaction
to generate exocyclic double bond (2a-c). Cycloaddition of nitrile oxides
and nitrile imines to the latter led to a novel spiro tetrahydrothiapyranoi
soxazolines (3a-f) and spiro tetrahydrothiapyranopyrazolines (4a-f).