ENANTIODIVERGENT SYNTHESIS OF A DECALIN TYPE OF CHIRAL BUILDING-BLOCKS AND THEIR APPLICATION TO TERPENOID SYNTHESIS

Authors
TOYOOKA N NISHINO A MOMOSE T
Citation
N. Toyooka et al., ENANTIODIVERGENT SYNTHESIS OF A DECALIN TYPE OF CHIRAL BUILDING-BLOCKS AND THEIR APPLICATION TO TERPENOID SYNTHESIS, Tetrahedron, 53(18), 1997, pp. 6313-6326
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
18
Year of publication
1997
Pages
6313 - 6326
Database
ISI
SICI code
0040-4020(1997)53:18<6313:ESOADT>2.0.ZU;2-V
Abstract
An enantiomeric pair of a decalin type of chiral building blocks beari ng an oxygenated angular substituent has been synthesized by the lipas e-mediated ring differentiation of a meso decahydronaphthalene glycol system Its synthetic utility has been demonstrated by the formal synth esis of (-)-polygodial, (-)-warburganal, (-)-drimenin, and (-)-elemol. (C) 1997 Elsevier Science Ltd.