The nanotribological properties of a hydrogen-terminated diamond(111)/tungs
ten-carbide interface have been studied using ultra-high vacuum atomic forc
e microscopy. Both friction and local contact conductance were measured as
a function of applied load. The contact conductance experiments provide a d
irect and independent way of determining the contact area between the condu
ctive tungsten-carbide AFM tip and the doped diamond sample. We demonstrate
that the friction force is directly proportional to the real area of conta
ct at the nanometer-scale. Furthermore, the relation between the contact ar
ea and load for this extremely hard heterocontact is found to be in excelle
nt agreement with the Derjaguin-Muller-Toporov continuum mechanics model.