First representatives of resorcinol bis(cyclophosphites) were synthesi
zed, on the basis of which a series of metallocomplexes, including a 1
6-membered binuclear metallocycle, was obtained. The fact that, in thi
s system, two m-phenylene cycles are almost parallel with each other m
akes possible the creation of complex polynuclear constructions. The p
hosphocyclane rings in resorcinol bis(cyclophosphites) an readily open
ed by bromine and chloramine to form bis-(omega-halogenoallylphosphate
s) of resorcinol.