RESORCINOL BIS(CYCLOPHOSPHITES)

Citation
Ee. Nifantyev et al., RESORCINOL BIS(CYCLOPHOSPHITES), Journal of organometallic chemistry, 529(1-2), 1997, pp. 171-176
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
529
Issue
1-2
Year of publication
1997
Pages
171 - 176
Database
ISI
SICI code
0022-328X(1997)529:1-2<171:RB>2.0.ZU;2-G
Abstract
First representatives of resorcinol bis(cyclophosphites) were synthesi zed, on the basis of which a series of metallocomplexes, including a 1 6-membered binuclear metallocycle, was obtained. The fact that, in thi s system, two m-phenylene cycles are almost parallel with each other m akes possible the creation of complex polynuclear constructions. The p hosphocyclane rings in resorcinol bis(cyclophosphites) an readily open ed by bromine and chloramine to form bis-(omega-halogenoallylphosphate s) of resorcinol.