SYNTHESIS OF 1-PHOSPHINOPHOSPHOLES AND THEIR TUNGSTENPENTACARBONYL COMPLEXES

Authors
SCHMIDT D KRILL S WANG B FRONCZEK FR LAMMERTSMA K
Citation
D. Schmidt et al., SYNTHESIS OF 1-PHOSPHINOPHOSPHOLES AND THEIR TUNGSTENPENTACARBONYL COMPLEXES, Journal of organometallic chemistry, 529(1-2), 1997, pp. 197-203
Citations number
52
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
529
Issue
1-2
Year of publication
1997
Pages
197 - 203
Database
ISI
SICI code
0022-328X(1997)529:1-2<197:SO1ATT>2.0.ZU;2-2
Abstract
A series of 1-phosphinophospholes 4a-d (R = tert-butyl (a), iso-propyl (b), ethyl (c), phenyl (d)) and their pentacarbonyltungsten complexes 5a-d are synthesized and characterized. The P-31 NMR patterns of both the complexed and free 1-phosphinophospholes follow similar trends. T he X-ray structure of 5a reveals an elongated P-P bond due to steric e ncumbrance, while the geometry of the phosphole moiety is not affected .