MOLYBDENUM CARBONYL-COMPLEXES OF DIPHOSPHINES AND TRIPHOSPHINES - HYDROPHOSPHINATION REACTIONS OF (HCCCH2PPH2)MO(CO)(5)

Authors
MAITRA K CATALANO VJ NELSON JH
Citation
K. Maitra et al., MOLYBDENUM CARBONYL-COMPLEXES OF DIPHOSPHINES AND TRIPHOSPHINES - HYDROPHOSPHINATION REACTIONS OF (HCCCH2PPH2)MO(CO)(5), Journal of organometallic chemistry, 529(1-2), 1997, pp. 409-422
Citations number
44
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
529
Issue
1-2
Year of publication
1997
Pages
409 - 422
Database
ISI
SICI code
0022-328X(1997)529:1-2<409:MCODAT>2.0.ZU;2-G
Abstract
The base catalyzed hydrophosphination reactions of (HC=CCH2PPh2)Mo(CO) (5) with Ph2PH and (Ph2PH)Mo(CO)(5) give several different products as a function of reaction conditions. These products were characterized by elemental analyses, physical properties, H-1, C-13{H-1}, and P-31{H -1} NMR spectroscopy, infrared spectroscopy, and in mast cases by X-ra y crystallography.