New synthetic method for dithiocarbamates

Citation
Rt. Li et al., New synthetic method for dithiocarbamates, CHEM J CH U, 20(12), 1999, pp. 1897-1902
Citations number
15
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790 → ACNP
Volume
20
Issue
12
Year of publication
1999
Pages
1897 - 1902
Database
ISI
SICI code
0251-0790(199912)20:12<1897:NSMFD>2.0.ZU;2-G
Abstract
In the presence of anhydrous potassium phosphate, different kinds of dithio carbamates were prepared from the reaction of primary amines, secondary ami nes and piperazine with carbon disulfate and a variety of alkyl halides at room temperature in high yields. It is not affected for the presence of -CO NR2, -OH, -CO2H,-NO2, -CO2R, -CH(OR)(2), -C = C-, -CH2OR, furan ring and sa ccharide ring in amine or alkyl halide.