Use of convexity for finding pure variables in two-way data from mixtures

Citation
Bv. Grande et R. Manne, Use of convexity for finding pure variables in two-way data from mixtures, CHEM INTELL, 50(1), 2000, pp. 19-33
Citations number
29
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS
ISSN journal
01697439 → ACNP
Volume
50
Issue
1
Year of publication
2000
Pages
19 - 33
Database
ISI
SICI code
0169-7439(20000104)50:1<19:UOCFFP>2.0.ZU;2-2
Abstract
The principles for finding pure (or key) variables in two-way non-negative data from mixtures are discussed. It is shown that with a normalization to constant projection on a given vector one obtains a convex and bounded repr esentation of the data with the pure variables as extreme points. An algori thm based upon this observation is compared with other methods for the same purpose and tested using data from the literature. (C) 2000 Elsevier Scien ce B.V. All rights reserved.