Phenomenological equations of the transfer of moisture and water-soluble co
mpounds in frozen grounds were derived and substantiated. Processes of the
migration of radionuclides in frozen grounds under the action of the gradie
nts of hydrostatic pressure, temperature, total concentration of water-solu
ble compounds, and concentration of radionuclides were considered. It was s
hown that experimental methods for the determination of the transfer charac
teristics and their assessment, and also the methods for predicting radionu
clide transfer processes in frozen grounds should provide a clear distincti
on between driving forces and fluxes of the convective and diffusion transf
er. The ratio between the convection and diffusion fluxes was estimated at
different concentrations of water-soluble compounds and temperature regimen
s. Based on the consideration of processes of the radionuclide transfer in
frozen grounds, measures providing a long-term localization of buried radio
active waste were recommended.