Ag. Karydas et T. Paradellis, MEASUREMENT OF KL AND LM RESONANT RAMAN-SCATTERING CROSS-SECTIONS WITH A PROTON-INDUCED CRK-ALPHA X-RAY-BEAM, Journal of physics. B, Atomic molecular and optical physics, 30(8), 1997, pp. 1893-1905
The resonant Raman effect has been described as an inelastic scatterin
g process occurring when the energy of the exciting x-ray beam approac
hes from below the energy of an absorption edge of a target element. I
t produces a scattered photon with a characteristic maximum energy and
the emission of an inner-shell electron. A high monochromatic CrKalph
a x-ray beam produced by protons was utilized for the measurement of t
he KL type of resonant Raman scattering (RRS) cross sections in V and
Cr and of the LM ones in La and Ce. In the case of V and Cr targets, t
he fluorescence yields of the KL-RRS process were also extracted, whil
e the fine-structure splitting in a LM-RRS spectrum was observed for t
he first time. The influence of RRS into different topics of x-ray spe
ctrometry, like the quantitative x-ray fluorescence analysis, the theo
retical calculations of the mass attenuation coefficients or the shape
of characteristic xrays emitted from low Z thick targets, is also dis
cussed.