Critical locus of aqueous solutions of sodium chloride

Citation
Aa. Povodyrev et al., Critical locus of aqueous solutions of sodium chloride, INT J THERM, 20(5), 1999, pp. 1529-1545
Citations number
27
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
INTERNATIONAL JOURNAL OF THERMOPHYSICS
ISSN journal
0195928X → ACNP
Volume
20
Issue
5
Year of publication
1999
Pages
1529 - 1545
Database
ISI
SICI code
0195-928X(199909)20:5<1529:CLOASO>2.0.ZU;2-Q
Abstract
Experimental data reported in the literature indicate a strong dependence o f the critical temperature of aqueous solutions of sodium chloride on salt concentration, especially in the limit of pure water. Critical pressures an d densities also show strong dependences on salt concentration. We propose a new set of equations for the critical locus and compare the results with evaluations reported previously by a number of investigators. The new equat ions yield a better description of the experimental data from the limit of pure water to the highest salt concentration for which data are available ( 0.3 mass fraction of sodium chloride).