The effects of water content and tempeature variation on the release of fla
vor components into the headspace over flavors, encapsulated by an extrusio
n process, in low water content carbohydrate matrixes is studied. The large
st amounts of release occurred when the matrix was above its glass transiti
on temperature, whether this was due to increased water content or elevated
temperature. Under these conditions up to 70% of the sucrose in the matrix
crystallized over a period of 10 days, as quantified using Fourier transfo
rm Raman spectroscopy. Smaller amounts of headspace release occurred when t
he water content of the encapsulated flavor system was decreased from 3.5 t
o 3.1% w/w. Small amounts of release occurred from the "as prepared" materi
als, which were associated with the presence of small amounts of unencapsul
ated flavor oil with direct access to the headspace. It was concluded that
release due to matrix permeability was relatively slow as compared with the
above mechanisms.