IONIC CONDUCTIVITIES OF PPO-LITFSI COMPLEXES

Authors
ROUX C SANCHEZ JY
Citation
C. Roux et Jy. Sanchez, IONIC CONDUCTIVITIES OF PPO-LITFSI COMPLEXES, Solid state ionics, 72, 1994, pp. 160-164
Citations number
7
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
72
Year of publication
1994
Part
2
Pages
160 - 164
Database
ISI
SICI code
0167-2738(1994)72:<160:ICOPC>2.0.ZU;2-H
Abstract
The ionic conductivity pattern of LiTFSI/poly (oxypropylene) complexes is investigated. Contrarily to previous data, related to several lith ium salt complexes, LiTFSI appears soluble in quite high concentration in PPO. The ionic conductivities are increased by more than one order of magnitude with respect to the more conductive compositions of PPO/ CF3SO3Li, Nevertheless, despite the good solubility of LiTFSI in this host polymer, a partial salt precipitation is observed for the more co ncentrated sample.