ION CONDUCTIVITY, ELECTRICAL RELAXATION AND ION ASSOCIATION IN POLY(PROPYLENE GLYCOL) COMPLEXED WITH AMMONIUM TRIFLATE

Ion conductivity and electrical relaxation have been studied in poly(p ropylene glycol) 4000 (PPG) complexed with NH4CF3SO3 in a concentratio n range of O:M=9800 to 10. A dielectric relaxation peak at about 1 MHz at room temperature is suggested to be due to ion pairs. Results indi cate that the electrical relaxation times associated with these peaks could act as a probe for the local flexibility of the polymer chains a nd that, in the concentration range studied, the fraction of ion pairs increases with increasing salt concentration. Other features of ion a ssociation are inferred from an analysis due to Pettit and Bruckenstei n. Ion conductivity in NH4SF3SO3, complexed with PPG is enhanced by a factor of 3 to 4 over that measured for LiCF3SO3 complexed PPG. Ion co nductivity in ND4CF3SO3 complexed PPG is used to comment on proton con duction in these systems.