Comparison of a range of rhodium-based catalysts for the hydroformylation of selected alkenes

Authors
Dickson, RS Bowen, J Campi, EM Jackson, WR Jonasson, CAM McGrath, FJ Paslow, DJ Polas, A Renton, P Gladiali, S
Citation
Rs. Dickson et al., Comparison of a range of rhodium-based catalysts for the hydroformylation of selected alkenes, J MOL CAT A, 150(1-2), 1999, pp. 133-146
Citations number
38
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN journal
13811169 → ACNP
Volume
150
Issue
1-2
Year of publication
1999
Pages
133 - 146
Database
ISI
SICI code
1381-1169(199912)150:1-2<133:COAROR>2.0.ZU;2-7
Abstract
Four rhodium-based catalyst systems (OC)(4)W(mu-PPh2)(2)RhH(CO)(PPh3) 1, (O C)(2)RhMo(CO)(3)(C5H4PPh2) 2, (OC)(2)RhW(CO)(3)(C5H4PPh2) 3. and [Rh(OAc)(2 )](2)/PPh3 have been used in the hydroformylation of 1-hexene, styrene and some phosphino-, amino- and amido-alkenes. In general the catalysts showed very similar reactivity and selectivity. (C) 1999 Elsevier Science B.V. All rights reserved.